NEET Chemistry Coordination Compounds MCQs Set B

Refer to NEET Chemistry Coordination Compounds MCQs Set B provided below available for download in Pdf. The MCQ Questions for Full Syllabus Chemistry with answers are aligned as per the latest syllabus and exam pattern suggested by NEET, NCERT and KVS. Multiple Choice Questions for Coordination Compounds are an important part of exams for Full Syllabus Chemistry and if practiced properly can help you to improve your understanding and get higher marks. Refer to more Chapter-wise MCQs for NEET Full Syllabus Chemistry and also download more latest study material for all subjects

MCQ for Full Syllabus Chemistry Coordination Compounds

Full Syllabus Chemistry students should refer to the following multiple-choice questions with answers for Coordination Compounds in Full Syllabus.

Coordination Compounds MCQ Questions Full Syllabus Chemistry with Answers

 

 

Question:  The total number of electrons donated by ligands to platinum ion in [Pt(en)2Cl2] is

  • a) 8
  • b) 10
  • c) 12
  • d) 14

Answer: 12

 

Question:  The IUPAC name of [Ni(CN)4]2– is

  • a) Tetracyanonickel (II) ion
  • b) Tetracyanonickelate (II) ion
  • c) Tetracyanonickel (0) ion
  • d) Tetracyanonickelate (0) ion

Answer: Tetracyanonickelate (II) ion

 

Question:  Out of following which ligand is a π acid ligand? 

  • a) CO
  • b) NH3
  • c) Cl
  • d) H2O

Answer: CO

 

Question: Which of the following is not an ambidentate ligand?

  • a) CN
  • b)

    NEET Chemistry Coordination Compounds Online Test Set A

  • c) SCN
  • d) NH3

Answer:  NH3

 

Question:  Primary and secondary valencies of Cu in [Cu(NH3)4]SO4 is

  • a) 4, 4
  • b) 2, 4
  • c) 4, 1
  • d) 4, 2

Answer: 2, 4

 

Question: Oxidation number of platinum in cis-platin

  • a) Zero
  • b) +2
  • c) +4
  • d) +6

Answer: +2

 

Question:  IUPAC name of K[BF4]

  • a) Potassium tetrafluoroborate
  • b) Tetrafluoroboron (III) potassium
  • c) Potassiumtetrafluoridoborate (III)
  • d) Tetrafluoridoboron (III) potassium

Answer: Potassiumtetrafluoridoborate (III)

 

Question:  Aq. solution of KCl.MgCl2.6H2O will give test of

  • a) K+ and Mg2+ only
  • b) K+ and Cl only 
  • c) K+, Mg2+ and Cl 
  • d) Mg2+ and H2O only

Answer:  K+, Mg2+ and Cl 

 

Question:  Aqueous solution of CoCl3.6NH3 upon addition with AgNO3 produces 3 moles white precipitate. Primary and secondary valency of metal in this complex is

  • a) 3, 6
  • b) 2, 6
  • c) 3, 3
  • d) 6, 4

Answer: 3, 6

 

Question: Which of the following complex is homoleptic?

  • a) H2[PtCl6
  • b) Li[AlH4]
  • c) [Ni(CO)4]  
  • d) All of these

Answer: All of these

 

Question: Structural formula of tetraaquadichloridochromium(III) chloride

  • a) [(H2O)4Cl2Cr]Cl2
  • b) [Cl2(H2O)4Cr]Cl3
  • c) [Cr(H2O)4Cl2]Cl
  • d) [Cr(H2O)4Cl3]

Answer:  [Cr(H2O)4Cl2]Cl

 

Question: Which of the following is not a polydentate ligand?

  • a) Oxalate ion
  • b) Ethylenediamine
  • c) Thiocyanato
  • d) EDTA

Answer: Thiocyanato

 

Question:  The complex [Cr(H2O)5Cl]Br and [Cr(H2O)5Br]Cl shows

  • a) Linkage isomerism
  • b) Ionisation isomerism
  • c) Hydrate isomerism
  • d) Co-ordination isomerism

Answer: Ionisation isomerism

 

Question: Oxidation number of platinum in cis-platin

  • a) Zero
  • b) +2
  • c) +4
  • d) +6

Answer: +2

 

Question: Which of the following octahedral complexes do not show geometrical isomerism?

  • a) [Co(NH3)3Cl3
  • b) [PtCl2(NH3)4]
  • c) [Pt(NH3)2Cl2]
  • d) [Co(en)3]3+

Answer:  [Co(en)3]3+

 

Question: Coordination isomerism exhibited by

  • a) [Cr(en)2Cl2]NO
  • b) [Co(NH3)5Br]SO4
  • c) [Pt(NH3)4] [CuCl4
  • d) [Co(NH3)5Cl]Cl2

Answer:  [Pt(NH3)4] [CuCl4

 

Question: Which one of the following complexes will have six isomers?

  • a) [Co(en)NH3Cl2]Cl  
  • b) [Cr(H2O)4Cl2]Cl
  • c) [Co(ox)3]3– 
  • d) [Co(en)2Br2]Cl

Answer:  [Co(en)2Br2]Cl

 

Question:  How many isomers are possible in [Cr(en)2Br2]?

  • a) 2
  • b) 3
  • c) 6
  • d) 1

Answer: 3

 

Question: The hybridisation of Ni in [Ni(CO)4] is

  • a) sp3 
  • b) dsp2
  • c) sp2
  • d) sp3d

Answer:  sp3 

 

Question: Which of the following is/are inner orbital complex?

  • a) [Fe(CN)6]4– 
  • b) [Cr(NH3)6]3+
  • c) [Mn(CN)6]3– 
  • d) All of these

Answer: All of these

 

Question:  Number of unpaired electrons present in [Ni(H2O)6]2+

  • a) Two
  • b) One
  • c) Four
  • d) Three

Answer: Two

 

Question: The spin magnetic moment of iron in K3[Fe(CN)6]

  • a) √3 BM
  • b) √5 BM 
  • c) √15 BM
  • d) √24 BM

Answer:  √3 BM

 

Question: Which one of the following is paramagnetic in nature?

  • a) Ni(CO)4
  • b) [Ni(CN)4]2– 
  • c) K4[Fe(CN)6]
  • d) [FeF6]4–

Answer:  [FeF6]4–

 

Question: Which of the following does not show optical activity?

  • a) [Co(NH3)4Cl2]  
  • b) [Cr(ox)3]3–
  • c) [Co(ox)2(NH3)2]Cl  
  • d) [Co(en)(NH3)2(H2O)2]Cl2

Answer: [Co(NH3)4Cl2]  

 

Question:  [Fe(H2O)6]3+ and [Fe(CN)6]3– differ in

  • a) Oxidation number
  • b) Coordination number
  • c) Structure
  • d) Magnetic nature

Answer: Magnetic nature

 

Question:  The spin only magnetic moment of [MnBr4]2– is 5.9 B.M. Geometry of the complex ion is

  • a) Tetrahedral
  • b) Octahedral
  • c) Square planar
  • d) Pentagonal pyramidal

Answer: Tetrahedral

 

Question: Which of the following statements are incorrect?

  • a) If Δ0< P, high spin state is more stable
  • b) NO2 is a strong ligand
  • c) Colour of a complex depends upon nature of metal ion only
  • d) Δ0> Δt

Answer: Colour of a complex depends upon nature of metal ion only

 

Question: According to crystal field theory, five d-orbitals of an octahedral complex split to give

  • a) Two orbitals with lower energy and three orbitals with higher energy
  • b) Three orbitals with lower energy and two orbitals with higher energy
  • c) One orbital with lower energy and four orbitals with higher energy
  • d) Four orbitals with lower energy and one orbital with higher energy

Answer: Three orbitals with lower energy and two orbitals with higher energy

 

Question: Which of the following complex is most stable?

  • a) [M(NH3)6]2+
  • b) [M(NH3)6]3+
  • c) [Men2(NH3)2]3+
  • d) [M(en)3]3+

Answer:  [M(en)3]3+

 

Question: In the formation of octahedral complex, ligands approach towards _______ and _______ orbital of central metal.

  • a) dxy,dx2- y2
  • b) dx2- y2,dz2
  • c) dxy, dyz
  • d) dz2, dxz 

Answer:  dx2- y2,dz2

 

More Questions............................................

 

Question:  Which reagent can be used to identify Ni2+ ion?

  • a) Resorcinol
  • b) Dimethyl glyoxime
  • c) Diphenyl benzidine
  • d) Potassium ferrocyanide

Answer: Dimethyl glyoxime

 

Question: Which of the following is not organometallic complex?

  • a) Grignard reagent
  • b) Ferrocene
  • c) Trans-platin
  • d) Diethyl zinc

Answer: Trans-platin

 

Question: Stability of the complex depends on

  • a) Oxidation state
  • b) Nature of ligand
  • c) Geometry of complex
  • d) All of these

Answer: All of these

 

Question:  π bonding is not involved in

  • a) Ferrocene
  • b) Dibenzene chromium
  • c) Zeise’s salt
  • d) Grignard reagent

Answer: Grignard reagent

 

Question: Which of the following will show optical activity?

  • a)

    NEET Chemistry Coordination Compounds Online Test Set B

  • b)

    NEET Chemistry Coordination Compounds Online Test Set B-Q2-2

  • c) [Co(NH3)6]3+
  • d)

    NEET Chemistry Coordination Compounds Online Test Set B-Q2-4

Answer:

NEET Chemistry Coordination Compounds Online Test Set B

 

Question: Which is a diamagnetic complex?

  • a) [Fe(H2O)6]3+ 
  • b) [Fe(H2O)6]2+
  • c) [Fe(CN)6]3–
  • d) [Fe(CN)6]4–

Answer:  [Fe(CN)6]4–

 

Question:  The hybridization of 'Cr' in the complex [Cr(NO2)4 (NH3)2]- is

  • a) sp3d2 
  • b) sp3d
  • c) d2sp3
  • d) sp3

Answer:  d2sp3

 

Question:  IUPAC name of H2[PtCl6] is

  • a) Dihydrogen hexachloridoplatinum (IV)
  • b) Hexachloridoplatinic (IV) acid
  • c) Dihydrogen hexachloridoplatinic (IV) acid
  • d) Hexachloridoplatinum (IV) acid

Answer: Hexachloridoplatinic (IV) acid

 

Question:  The geometry of [Ni(CO)4] and [PdCl4]2– respectively are

  • a) Both are tetrahedral
  • b) Both are square planar
  • c) Square planar and tetrahedral
  • d) Tetrahedral and square planar

Answer: Tetrahedral and square planar

 

Question:  Write the increasing order of the value is CFSES (Δ0) for the following species

I. [Co(NH3)6]3+

II. [Rh(NH3)6]3+

III. [Ir(NH3)6]3+

  • a) III < II < I
  • b) I < II < III
  • c) II < I < III
  • d) I < III < II

Answer: I < II < III

 

Question: Which of the following is correct statement?

  • a) [Ti(H2O)6]3+ is coloured complex
  • b) [Si(H2O)6]4+ is colourless complex
  • c) d - d transition is not possible in [Si(H2O)6]4+ complex
  • d) All of these

Answer: All of these

 

 

Question: Which of the following will have greatest molar conductance at infinite dilution?

 

  • a) [Pt(NH3)5Cl]Cl3
  • b) [Pt(NH3)4Cl2]Cl2
  • c) [Pt(NH3)2Cl4]  
  • d) [Pt(NH3)6]Cl4

Answer:  [Pt(NH3)6]Cl4

 

Question: Which of the following is the high spin complex?

  • a) [Cr(gly)3]
  • b) [CoBr2Cl2(SCN)2]3–
  • c) [Fe(CN)6]3– 
  • d) Na[PtBrCl(NO2)2(NH3)2]

Answer:  [CoBr2Cl2(SCN)2]3–

 

Question:  The coordination number and magnetic moment of the complex [Cr(C2O4)2(NH3)2] respectively is

  • a) 6, 3.87 BM
  • b) 4, 3.87 BM
  • c) 6, 3.46 BM
  • d) 4, 1.73 BM

Answer: 6, 3.87 BM

 

Question: Number of geometrical isomers possible for [MABCDEF] is

  • a) 6
  • b) 10
  • c) 15
  • d) 12

Answer: 15

 

Question: How many optical isomers are possible for [MABCD]?

  • a) 1
  • b) 2
  • c) 3
  • d) Zero

Answer: Zero

 

Question:  [Ni(gly)2] shows two stereoisomers. Those are

  • a) Geometrical
  • b) Optical
  • c) Does not show isomerism
  • d) Both (1) & (2)

Answer: Optical

 

Question:  Naming of ligand in [M(en)2]n+ starts with

  • a) Di
  • b) Bi
  • c) Bis
  • d) Any of these

Answer: Bis

 

Question: Which of the following has primary valency “2”?

  • a) [Co(NH3)5Cl]Cl
  • b) [Co(NH3)4Cl2]Cl
  • c) [Co(NH3)3Cl3]
  • d) [Co(H2O)4Cl2]Cl

Answer:  [Co(NH3)5Cl]Cl

 

Question:  If the value of C.F.S.E. for “Ni” is Δ0 then it is for Pd should be

  • a) 1.1Δ0
  • b) 0.5 Δ0
  • c) 1.5 Δ0
  • d) 2 Δ0

Answer: 1.5 Δ0

 

Question: Ligand to form a complex which is used to treat hard water

  • a) NH3
  • b) ox
  • c) en
  • d) EDTA

Answer: EDTA

 

Question: Which of the following is not bidentate ligand?

  • a) acac
  • b) ox
  • c) en
  • d) dien

Answer: dien

 

Question: Which of the following is flexidentate?

  • a) CO
  • b) en
  • c) EDTA
  • d) Cl

Answer: EDTA

 

Question: The value of ‘spin only’ magnetic moment, follows the correct order?

  • a) [Fe(CN)6]4– > [CoCl4]2– > [MnCl4]2–
  • b) [MnCl4]2– > [Fe(CN)6]4– > [CoCl4]2–
  • c) [Fe(CN)6]4– > [MnCl4]2– > [CoCl4]2–
  • d) [MnCl4]2– > [CoCl4]2– > [Fe(CN)6]4–

Answer:  [MnCl4]2– > [CoCl4]2– > [Fe(CN)6]4–

 

Question: How many hydrogen bonded water molecules are present in blue vitriol?

  • a) Zero
  • b) One
  • c) Four
  • d) Five

Answer: One

 

Question:  If  Δ0 is the crystal field stabilisation energy of a ligand and P is the energy required for electron pairing in an orbital, then ligand is called weak ligand if

  • a) Δ0> P
  • b) Δ0< P 
  • c) Δ0= P 
  • d) Unpredictable

Answer:  Δ0< P 

 

Question: The complex compound bearing square planar geometry is

  • a) Ni(CO)4
  • b) [Ni(CN)4]2–
  • c) [Mn(CN)6]3–
  • d) [MnCl4]2–

Answer:  [Ni(CN)4]2–

 

Question: The complex compound having maximum magnetic moment is

  • a) [CoF6]3– 
  • b) [Cr(NH3)6]3+
  • c) [FeF6]3– 
  • d) [Mn(CN)6]4–

Answer: [FeF6]3– 

 

Question:  Which of the following is not π-acid ligand?

  • a) CO
  • b) F 
  • c) C2H4
  • d) NO+

Answer:  F 

 

Question: The complex compound in which metal is not present in zero oxidation state?

  • a) Mn2(CO)10
  • b) [Ni(CO)4]
  • c) [Cr(C6H6)2]
  • d) K[PtCl3(C2H4)]

Answer:  K[PtCl3(C2H4)]

 

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