NEET Chemistry Chemical Bonding and Molecular Structure MCQs Set B

Refer to NEET Chemistry Chemical Bonding and Molecular Structure MCQs Set B provided below available for download in Pdf. The MCQ Questions for Full Syllabus Chemistry with answers are aligned as per the latest syllabus and exam pattern suggested by NEET, NCERT and KVS. Multiple Choice Questions for Chemical Bonding and Molecular Structure are an important part of exams for Full Syllabus Chemistry and if practiced properly can help you to improve your understanding and get higher marks. Refer to more Chapter-wise MCQs for NEET Full Syllabus Chemistry and also download more latest study material for all subjects

MCQ for Full Syllabus Chemistry Chemical Bonding and Molecular Structure

Full Syllabus Chemistry students should refer to the following multiple-choice questions with answers for Chemical Bonding and Molecular Structure in Full Syllabus.

Chemical Bonding and Molecular Structure MCQ Questions Full Syllabus Chemistry with Answers

 

 

Question:  The molecular orbital shown below can be described respectively as

NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q31

  • a)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q31-1

  • b)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q31-2

  • c)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q31-3

  • d)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q31-4

Answer:

NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q31-3

 

Question: The hybrid orbital having only 20% d character

  • a) CCl4 
  • b) SF6
  • c) SF4
  • d) Cl2O

Answer:  SF4

 

Question: Which of the following molecule stabilizes by removal of electron?

  • a) C2
  • b) O2
  • c) N2
  • d) H2

Answer:  O2

 

Question: Which of the following statement is correct?

  • a) The hybridisation of Cl in ClF3   is sp2
  • b) The number of lone pairs and bond pairs in I3 are 2 and 2 respectively
  • c) The shape of XeF6  is distorted square bipyramidal
  • d) Hybridisation of S is sp3 in SO2

Answer: The shape of XeF6  is distorted square bipyramidal

 

Question:  The formal charges of oxygen labelled 3,2,1 in ozone respectively are

NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q35

  • a) –1, +1, 0
  • b) 0, 0, –1
  • c) –1, 0, +1
  • d) 0, +1, –1

Answer: –1, 0, +1

 

Question:  Number of nodal planes in π*2pare

  • a) Zero
  • b) One
  • c) Two
  • d) Three

Answer: Two

 

Question: Which of the following is not a correct statement?

  • a) Multiple bonds are always shorter than corresponding single bonds
  • b) The electron-deficient molecules can act as Lewis acids
  • c) The canonical structures have no real existence
  • d) Every AB5 molecules does in fact have square pyramid structure

Answer:  Every AB5 molecules does in fact have square pyramid structure

 

Question:  Some of the properties of the two species, NO3- and H3O+ are described below. Which one of them is correct?

  • a) Dissimilar hybridization for the central atom with different structures
  • b) Isostructural with same hybridization for the central atom
  • c) Isostructural with different hybridization for the central atom
  • d) Similar hybridization for the central atom with different structures

Answer: Dissimilar hybridization for the central atom with different structures

 

Question:  The ground state electronic configuration of valence shell electrons in nitrogen molecule (N2) is written as kk,

NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q3

Hence the bond order in nitrogen molecule is

  • a) 2
  • b) 3
  • c) 0
  • d) 1

Answer: 3

 

Question: A certain diatomic molecule, AB has dipole moment 1.6 D and the internuclear distance is 100 pm. The percentage of electronic charge existing on more electronegative atom is

  • a) 33%
  • b) 25%
  • c) 50%
  • d) 10%

Answer: 33%

 

Question:  Which of the following is correct for XeO2F2  and PCl5 ?

  • a) Both have same hybridisation and shape
  • b) Both have same hybridisation but different geometry
  • c) Both have different hybridisation but same shape
  • d) Both have same hybridisation but different shape

Answer: Both have same hybridisation but different shape

 

Question:  The maximum number of 180° angle possible between X-M-X bond for compounds with sp3d2 and sp3d  hybridisation respectively are

  • a) 3, 3
  • b) 3, 1
  • c) 1, 3
  • d) 3, 0

Answer: 3, 1

 

Question:  The shape for the molecule with general formula AF6 with one lone pair can be represented as

  • a)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q6-1

  • b)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q6-2

  • c)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q6-3

  • d)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q6-4

Answer:

NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q6-4

 

Question:   Which of the following is correct representation of dipole moment of NH3 molecule?

  • a)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q7

  • b)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q7-1

  • c)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q7-2

  • d)  NHbeing symmetrical will not show dipole moment

Answer:

NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q7-1

 

Question: Incorrect statement regarding hybridization is

  • a) It is not possible for isolated atoms
  • b) Number of hybrid orbital formed is same as the number of orbitals combining
  • c) Only the half filled orbitals and fully filled orbitals can participate not the empty orbital
  • d) It is not a real physical process

Answer: Only the half filled orbitals and fully filled orbitals can participate not the empty orbital

 

Question:  Dipole moment of  is

NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q7-3

1.1 D hence dipole moment of given compound will be

NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q7-4

  • a) 1.1 D
  • b) 4.4 D
  • c) 3.3 D
  • d) 2.56 D

Answer: 1.1 D

 

Question:   In

NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q8

hybrid state of N atom is

  • a) sp
  • b) sp3
  • c) sp3d2
  • d) sp

Answer:  sp3

 

Question: Which molecule contains both polar and non-polar covalent bond?

  • a) NH4+
  • b) HCl
  • c) CH4 
  • d) H2O2

Answer:  H2O2

 

Question:  The shape of I3 is

  • a) Linear
  • b) Bent
  • c) Pyramidal
  • d) See saw

Answer: Linear

 

Question:  Which of the following statements are correct?

I. Bond order of NO is 2.5

II. Bond order of NO+ is 3.0

III. Bond order of O2 is 1.5

IV. Bond order of CO is 3.0

  • a) I, II, III
  • b) II, III, IV
  • c) I, II, IV
  • d) II, IV

Answer: I, II, IV

 

Question:  Arrange the following species in increasing order of bond angle NF3, NCl3, NBr3,NI3

  • a) NF3< NCl3< NBr3< NI3 
  • b) NF3< NBr3< NI3< NCI3 
  • c) NI3< NBr3< NCl3< NF3
  • d) NBr3< NI3< NF3< NCl3

Answer: NF3< NCl3< NBr3< NI3 

 

Question:  o-nitrophenol is

  • a) More volatile than p-nitrophenol
  • b) Less volatile than p-nitrophenol
  • c) Equally volatile as p-nitrophenol
  • d) Non-volatile

Answer: More volatile than p-nitrophenol

 

Question: How many bonds are formed by each oxygen atom in ice?

  • a) 4
  • b) 2
  • c) 3
  • d) May be 1 or 2

Answer: 4

 

Question:  Which of the following pair consists of only paramagnetic species?

  • a) H2, O2+
  • b) N2, O2 
  • c) CO, N2  
  • d) H2+, O2

Answer: H2+, O2

 

Question: Number of angles of 109°28' is present in CCl4

  • a) 2
  • b) 4
  • c) 6
  • d) 8

Answer: 6

 

Question:  Number of carbon atoms present in sp2 hybrid state of given molecule?

NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q8-1

  • a) 9
  • b) 8
  • c) 3
  • d) 2

Answer: 8

 

Question: According to octet rule the compound which contain ionic, covalent and coordinate bonds

  • a) CaSO4
  • b) NH4Cl 
  • c) NaNO3
  • d) All of these

Answer: All of these

 

Question: Which of the following molecule is having least ionic character?

  • a) FeCl2 
  • b) ZnCl2 
  • c) MgCl2
  • d) NaCl

Answer:  ZnCl2 

 

Question: In the given structure of a compound, the correct various bond moments direction involving atoms are shown as

  • a)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q24

  • b)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q24-2

  • c)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q24-3

  • d)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q24-4

Answer:

NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q24-3

 

Question:  The number of antibonding electron pairs in O2

  • a) 2
  • b) 3
  • c) 1
  • d) 4

Answer: 3

 

More Questions.............................

 

Question:  In PO43– ion, the effective charge on each oxygen atom and P–O bond order respectively are

  • a) –0.75, 1.25
  • b) –0.75, 1.0
  • c) –0.75, 0.6
  • d) –3, 1.25

Answer: –0.75, 1.25

 

Question: Which of the following is a polar molecule?

  • a) Para dichlorobenzene
  • b) Carbon tetrachloride
  • c) Tetrachloroethene
  • d)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q24-5

Answer:

NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set A-Q24-5

 

Question:   In a regular trigonal bipyramidal MX5  , the number of X – M – X bonds at 180º is

  • a) One
  • b) Two
  • c) Six
  • d) Four

Answer: One

 

Question: Maximum bond angle at nitrogen is present in which of the following?

  • a) NO3-
  • b) NO2  
  • c) NO2-
  • d) NO2+

Answer:  NO2+

 

Question: Which of the following molecules has the maximum dipole moment?

  • a) CO2
  • b) CH4
  • c) NH3
  • d) NF3

Answer:  NH3

 

Question: Which one of the following species has plane triangular shape?

  • a) N 
  • b) NO3 
  • c) NO2 
  • d) CO2

Answer: NO2 

 

Question: Which one of the following molecules contains no π bond? 

  • a) H2
  • b) SO2 
  • c) NO2
  • d) CO2

Answer: H2

 

Question: Which of the following is a polar molecule?

  • a) SF
  • b) SiF4
  • c) XeF4  
  • d) BF3

Answer:  SF

 

Question: Which of the following is paramagnetic?

  • a) O2 
  • b) CN
  • c) NO
  • d) CO

Answer:  O2 

 

Question: The pair of species with the same bond order is

  • a) NO, CO
  • b) N2, O2
  • c) O22–, B2
  • d) O2+, NO+

Answer: O22–, B2

 

Question: Bond order of 1.5 is shown by

  • a) O22- 
  • b) O2
  • c) O2+ 
  • d) O2-

Answer:  O2-

 

Question: Which one of the following pairs is isostructural (i.e. having the same shape and hybridization)?

  • a) [NF3 and BF3
  • b) [BF4-  and NH4+
  • c) [BCl3 and BrCl3
  • d) [NH3 and NO3]

Answer:  [BF4-  and NH4+

 

Question:  During change of O2  to O22– ion, the electron adds on which one of the following orbitals?

  • a) π* orbitals
  • b) π orbitals 
  • c) σ* orbitals 
  • d) σ orbitals

Answer: π* orbitals

 

Question: Four diatomic species are listed below. Identify the correct order in which the bond order is increasing in them

  • a)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B

  • b)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B-2

  • c)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B-3

  • d)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B-4

Answer:

NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B-4

 

Question: Which of the following has the minimum bond length?

  • a) O2
  • b) O2+ 
  • c) O2– 
  • d) O22

Answer:  O2+ 

 

Question: The correct order of increasing bond length of C – H, C – O, C – C and C = C is 

  • a) C – H < C – O < C – C < C = C 
  • b) C – H < C = C < C – O < C – C
  • c) C – C < C = C < C – O < C – H
  • d) C – O < C – H < C – C < C = C

Answer:  C – H < C = C < C – O < C – C

 

Question:  Which of the two ions from the list given below that have the geometry that is explained by the same hybridization of orbitals

NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B-5

 

  • a)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B-14-

  • b)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B-14-2

  • c)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B-14-3

  • d)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B-14-4

Answer:

NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B-14-2

 

Question:  Which of the following structures is the most preferred and hence of lowest energy for SO3?

  • a)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B-15

  • b)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B-15-2

  • c)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B-15-3

  • d)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B-15-4

Answer:

NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B-15-2

 

Question: The pairs of species of oxygen and their magnetic behaviours are noted below. Which of the following presents the correct description?

  • a)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B-16-1

  • b)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B-16-2

  • c)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B-16-3

  • d)

    NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B-16-4

Answer:

NEET Chemistry Chemical Bonding and Molecular Structure Online Test Set B-16-1

 

Question: Which one of the following species does not exist under normal conditions?

  • a) Be2+
  • b) Be2 
  • c) B2 
  • d) Li2

Answer:  Be2 

 

Question: The angular shape of molecule (O3) consists of

  • a) 2 sigma and 1 pi bond
  • b) 1 sigma and 2 pi bonds
  • c) 2 sigma and 2 pi bonds
  • d) 1 sigma and 1 pi bond

Answer: 2 sigma and 1 pi bond

 

Question: Which of the following is not a correct statement?

  • a) The electron-deficient molecules can act as Lewis acids
  • b) The canonical structures have no real existence
  • c) Every AB5 molecule does in fact have square pyramid structure
  • d) Multiple bonds are always shorter than corresponding single bonds

Answer:  Every AB5 molecule does in fact have square pyramid structure

 

Question: The number of unpaired electrons in a paramagnetic diatomic molecule of an element with atomic number 16 is

  • a) 2
  • b) 3
  • c) 4
  • d) 1

Answer: 2

 

Question: Which of the following molecules has trigonal planar geometry?

  • a) IF3
  • b) PCl3
  • c) NH3
  • d) BF3

Answer:  BF3

 

Question: Which of the following would have a permanent dipole moment ?

  • a) BF3
  • b) SiF4
  • c) SF4
  • d) XeF4

Answer: SF4

 

Question: Which one of the following oxides is expected to exhibit paramagnetic behaviour?

  • a) CO2
  • b) SO2
  • c) CIO2
  • d) SiO2

Answer:  CIO2

 

Question:  The geometry of electron pairs around I in IF5  is

  • a) Octahedral
  • b) Trigonal bipyramidal
  • c) Square pyramidal
  • d) Pentagonal planar

Answer: Octahedral

 

Question:  The structure and hybridization of Si(CH3)4  is

  • a) Octahedral, sp3d
  • b) Tetrahedral, sp3
  • c) Bent, sp
  • d) Trigonal, sp2

Answer:  Tetrahedral, sp3

 

Question:  The number of bonding electron pairs in N2 on the basis of molecular orbital theory is

  • a) 3
  • b) 2
  • c) 5
  • d) 4

Answer: 5

 

Question: Cation and anion combines in a crystal to form following type of compound

  • a) Ionic
  • b) Metallic
  • c) Covalent
  • d) Dipole-dipole

Answer: Ionic

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