NEET Chemistry Alcohols Phenols And Ethers Revision Notes

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Revision Notes for Full Course Alcohol Phenol and Ether Alcohols Phenols And Ethers

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Alcohols Phenols And Ethers Notes Full Course Alcohol Phenol and Ether

 

Revision Notes on Alcohols, Phenols and Ether:
Alcohols
 
Preparation of Alcohols:
 
¶ By hydrolysis of haloalkanes : R-X + aq. KOH →ROH +KX
¶ By reduction of Carbonyl compounds
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction
•  Hydroboration-oxidation:
 
 
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-1
 
 
 
•  Hydroxylation of alkenes:
 
 
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-2
 
Physical Properties of Alcohol:
 
• Lower alcohols are liquid at room temperature while higher ones are solid.
•  High boiling point due to presence of intermolecular hydrogen bonding. Order of Boiling Point:
primary > secondary > tertiary
•  Solubility in water decreases with increase in molecular mass due to decrease in extent of intermolecular hydrogen bonding.
 
Chemical Properties of Alcohol:
•  Alcohol's reaction with metal: ROH + Na→2RO+Na + H2
•  Formation of Halides:
 
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-3
 
• Reaction with HNO3: R-OH + HO-NO2→ R-O-NO2
• Reaction with carboxylic acid (Esterification) : R-OH +R’-COOH +H+↔ R’-COOR
• Reaction with Grignard reagent: R'OH + RMgX → RH + R'OMgX
• Reduction of alcohol : ROH + 2HI + Red P→ RH +I2+H2O
• Dehydration of Alcohol: Dehydration of alcohols takes place in acidic medium. Intra-molecular dehydration leads to the formation of alkene while inter molecular dehydration which forms ether. Ease of dehydration: 3° > 2° > 1
•  Satyzeff’s Rule : Elimination through b carbon containing minimum b hydrogen
 
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-4
 
•  Oxidation of Alcohol:
 
RCH2-OH + [O] → RCHO → RCOOH
RCH2-OH + [O]+PCC → RCHO
 
 
•  Haloform Reaction: Compound containing CH3CO- group (or compound on oxidation gives CH3CO– group) which is attached with a C or H, in presence of halogen and mild alkali gives haloform.CH3-CH2-COCH2-CH3, CH3-CO-Cl, CH3COOH will not respond to haloform reaction while CH3CH2OH will respond to haloform Reaction.
 
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-5
 
Test for Alcohols:
 
1. Lucas Test:
 
Alcohols + ZnCl2 + HCl
 1o Alcohol: RCH2OH + ZnCl2 +HCl → No reaction at room temperature
 2o Alcohol: R2CHOH + ZnCl2 +HCl → R2CHCl White turbidity after 5-10 min.
 3o Alcohol: R3CHOH + ZnCl2 +HCl → R3CHCl white turbidity instantaneously.
 
2. Victor Meyer Test
 
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-6
 
 
Phenols:
Preparation:
 
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-7
 
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-8
 
 
Physical Properties of Phenols
• Phenol is a colorless, toxic, corrosive, needle shaped solid.
• Phenol soon liquifies due to high hygroscopic nature.
• Phenol is less soluble in water, but readily soluble in organic solvents.
• Simplest phenols, because of hydrogen bonding have quite high boiling points.
• o-nitrophenol is, steam volatile and also is less soluble in water because of intramolecular hydrogen bonding
 
Chemical Properties of Phenols
a) Formation of Esters
Phenyl esters (RCOOAr) are not formed directly from RCOOH. Instead, acid chlorides or anhydrides are reacted with ArOH in the presence of strong base
(CH3CO)2O + C6H5OH + NaOH → CH3COOC6H5 + CH3COONa + H2O
                                                 Phenyl acetate
C6H5COCl + C6H5OH + NaOH → C6H5COOC6H5 + Na+Cl + H2O
                                               Phenyl benzoate
 
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-9
 
e) Electrophilic Substitution: The —OH and even more so the —O(phenoxide) are strongly activating ortho ,para - directing
 
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-10
 
Special mild conditions are needed to achieve electrophilic monosubstituion in phenols because their high reactivity favors both polysubstitution and oxidation.
 
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-11
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-12
 
 
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-13
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-14
 
 
Ethers:
Physical Properties of Ethers
 
• Physical state, colour and odour: Dimethyl ether and ethyl methyl ether is gas at ordinary temperature while the other lower homologues of ethers are colourless liquid with characteristic 'ether smell'.
• Dipole nature: Ethers have a tetrahedral geometry i.e., oxygen is sp3 hybridized. The C— O—C angle in ethers is 110°. Because of the greater electronegativity of oxygen than carbon, the C—O bonds are slightly polar and are inclined to each other at an angle of 110°, resulting in a net dipole moment.
 
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-15
 
 
Bond angle of ether is greater than that of tetrahedral bond angle of 109°28'.
 
• Solubility and boiling point: Due to the formation of less degree of hydrogen bonding, ethers have lower boiling point than their corresponding isomeric alcohols and are slightly soluble in water.
 
Preparation of Ethers:
 
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-16
 
From Grignard reagent: Treating a - halo ethers with suitable Grignard reagents.
 
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-17
On standing in contact with air, most aliphatic ethers are converted slowly into unstable peroxides.The presence of peroxides is indicated by formation of a red colour when the ether is shaken with an aqueous solution of ferrous ammonium sulfate and potassium thiocyanate
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-18
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Table
 
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-19
 
i) Reaction with acid chlorides and anhydrides:
 
j) Electrophilic substitution reactions
 
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-20
 
Epoxides or Oxiranes:
 
Preparation
a) Oxidation of ethylene :
 
NEET Chemistry Alcohols Phenols and Ethers Revision Notes Reaction-21
 
 

NEET Full Course Alcohol Phenol and Ether Alcohols Phenols And Ethers Notes

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