CBSE Class 12 Chemistry Amines Assignment

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Assignment for Class 12 Chemistry Unit 13 Amines

Class 12 Chemistry students should refer to the following printable assignment in Pdf for Unit 13 Amines in Class 12. This test paper with questions and answers for Class 12 Chemistry will be very useful for exams and help you to score good marks

Unit 13 Amines Class 12 Chemistry Assignment

 
Level one

1) Write IUPAC names of the following compounds and classify them into primary,secondary andteritary amines.
a) (CH3)2CHNH2
Ans: propan-2-amine(primary)
 
b)CH3(CH2)2NH2
Ans: propan-1-amine(primary)
 
c)CH3NHCH(CH3)2
Ans: N-Methyl propan-2-amine(secondary)
 
d)(CH3)3CNH2
Ans: 2-Methylpropan-2-amine (primary)
 
e)C6H5NHCH3
Ans:  N-Methylaniline (secondary)
 
f)m-BrC6H4NH2
Ans: 3- Bromobenzenamine(primary)
 
2) Give one chemical test to distinguish between the following pairs of compounds.
 
a) Methylamine and dimethylamine
Ans: Methyl amine being a 1° amine will give carbyl amine test,while dimethylamine,a 2° amine will not give this test.
 
b)Ethylamine and aniline
Ans: Aniline will give brilliantly coloured orange dye on diazotization and coupling with phenol. ethylammine on treatment with HNO3(NaOH+HCl) gives N2 and ethanol fails to couple with phenol to give adye
 
d)Aniline and benzylamine
Ans: Aniline (an aromatic primary amine) will give brilliantly coloured orange dye on diazotization and coupling with phenol.Benzylamine which is not an aromatic primary amine will not give this test. It only give N2 and benzyl alcohol with HNO2.
 
e)Aniline and N-methylaniline
Ans: Aniline is a primary amine it will give carbyl amine test while N-methylaniline is a secondary amine,and as such it will not give carbyamine test.
 
3) Arrange the following :

a) In decreasing order of the pKb values:
Ans: C6H5NH2>C6H5NHCH+>C2H5NH2>(C2H5)2NH

b) In increasing order of basic strength:
C6H5NH2, C6H5N(CH3)2, (C2H5)2NH and CH3NH2
Ans: C6H5NH2<C6H5N(CH3)2< CH3NH2<(C2H5)2NH

c) In increasing order of basic strength:
a) Aniline, p-nitroniline and p-toluidine
b) C6H5NH2 , C6H5NHCH3, C6H5CH2NH2
Ans: a)p-nitroaniline<aniline<p-toluidine
b)C6H5NH2<C6H5NHCH3<C6H5CH2NH2

d) In decreasing order of basic strength in gas phase:
C2H5NH2, (C2H5)2NH, (C2H5)3N and NH3
Ans: (C2H5)3N>(C2H5)2NH> C2H5NH2> NH3

e) In increasing order of boiling point:
C2H5OH, (CH3)2NH, C2H5NH2
Ans: (CH3)2NH< C2H5NH2< C2H5OH

f) In increasing order of solubility in water:
C6H5NH2, (C2H5)2NH, C2H5NH2
Ans: C6H5NH2<(C2H5)2NH< C2H5NH2

4) Write short notes on the following:

i) Carbylamine reaction :All primary amines on heating with chloroform and an alcoholic solution of potassium hydroxide produce isocyanide

ii)Diazotisation:The conversion of aniline or other aromatic primary amines into diazonium salts by the action of nitrous acid and dilute hydrochloric acid is called diazotization.

iii)Hofmann’s bromamide reaction :The heating of amine an amide with bromine and caustic alkali to yield an amine with one carbon less than the original amide this reaction is called Hofmann’s bromamide reaction.

iv)Coupling reaction:Reaction of aromatic diazinium salt with phenols and amines to give azo compounds is called coupling reaction.

v)Ammonolysis :Alkyl halides react with alcoholic ammonia to primary,secondary and tertiary amines along with some quaternary ammonium salts.
 
 
Please click the link below to download CBSE Class 12 Chemistry Amines Assignment

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CBSE Class 12 Chemistry Unit 13 Amines Assignment

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