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Worksheet for Class 10 Science Chapter 4 Carbon and Its Compound
Class 10 Science students should refer to the following printable worksheet in Pdf for Chapter 4 Carbon and Its Compound in Class 10. This test paper with questions and answers for Class 10 will be very useful for exams and help you to score good marks
Class 10 Science Worksheet for Chapter 4 Carbon and Its Compound
Question. CH, The IUPAC name of CH-C-CH-CH, is CH,
(a) 2-ethyl-2-methyl propane
(b) 1, 1, 1-trimethyl propane
(c) 2, 2-demethyl butane
(d) 2, 2-methyl butane
Answer : B
Question. Ethane and ethene can be distinguished by
(a) Br2(l)
(b) Br2 (aq) water
(c) Cl2
(d) I2
Answer : B
Question. Carbon exists in the atmosphere in the form of
(a) carbon monoxide only
(b) carbon monoxide in traces and carbon dioxide
(c) carbon dioxide only
(d) coal
Answer : B
Question. When ethanoic acid is treated with NaHCO^ the gas evolved is
(a) H2
(b) CO2
(c) CH4
(d) CO
Answer : B
Question. The self linkage property (catenation) is maximum in
(a) carbon
(b) silicon
(c) sulphur
(d) phosphorus
Answer : A
Question. A soap molecule has a
(a) hydrophobic head and hydrophobic tail
(b) hydrophobic head and hydrophilic tail
(c) hydrophilic head and hydrophilic tail
(d) hydrophilic head and hydrophobic tail
Answer : D
Question. Ethanol on complete oxidation gives
(a) acetic acid/ethanoic acid
(b) CO2 and water
(c) ethanal
(d) acetone/ethanone
Answer : B
Question. Which of the following will give a pleasant smell of ester when heated with ethanol and a small quantity of sulphuric acid?
(a) CH3COOH
(b) CH3CH2OH
(c) CH3OH
(d) CH3CHO
Answer : A
Question. Name the functional group present in CH3COCH3.
(a) Alcohol
(b) Carboxylic acid
(c) Ketone
(d) Aldehyde
Answer : C
Question. Why does carbon form compounds mainly by covalent bonding?
(a) There are four electrons in the outermost shell of carbon.
(b) It requires large amount of energy to form C4+ or C4sup>4-.
(c) It shares its valence electrons to complete its octet.
(d) All the above.
Answer : D
Question. Which of the following statements are correct for carbon compounds?
(i) Most carbon compounds are good conductors of electricity.
(ii) Most carbon compounds are poor conductors of electricity.
(iii) Force of attraction between molecules of carbon compounds is not very strong.
(iv) Force of attraction between molecules of carbon compounds is very strong.
(a) (ii) and (iv)
(b) (ii) and (iii)
(c) (i) and (iv)
(d) (i) and (iii)
Answer : B
Question. Identify ‘A’ in the following reaction:
CH3COOH + Na2CO3 → A + CO2 + H0O
(a) CH3COONa
(b) CH2(Na)COOH
(c) NaOH
(d) NaHCO3
Answer : A
Question. Which of the following belongs to homologous series of alkynes?
C6H6, C2H6, C2H4, C3H4.
(a) C6H6
(b) C2H4
(C) C2H6
(d) C3H4
Answer : D
Question. A hydrocarbon has four carbon atoms. Give its molecular formula if it is an alkene.
(a) C4H10
(b) C4H8
(C) C4H6
(d) C4H4
Answer : B
Question. The number of isomers of pentane is
(a) 2
(b) 3
(c) 4
(d) 5
Answer : B
Question. In diamond, each carbon atom is bonded to four other carbon atoms to form
(a) a hexagonal array
(b) a rigid three-dimensional structure
(c) a structure in the shape of a football
(d) a structure of a ring
Answer : B
Question. Carbon forms four covalent bonds by sharing its four valence electrons with four univalent atoms, e.g. hydrogen. After the formation of four bonds, carbon attains the electronic configuration of
(a) helium
(b) neon
(c) argon
(d) krypton
Answer : B
Question. A molecule of ammonia (NH3) has
(a) only single bonds
(b) only double bonds
(c) only triple bonds
(d) two double bonds and one single bond
Answer : A
Question. Oils on treating with hydrogen in the presence of palladium or nickel catalyst form fats. This is an example of
(a) Addition reaction
(b) Substitution reaction
(c) Displacement reaction
(d) Oxidation reaction
Answer : A
Question. A functional group mainly determines the
(a) physical properties
(b) chemical properties
(c) both
(d) none of these
Answer : B
Question. The blindness and death is caused by consuming adultrated liquor contains.
(a) CH3OH
(b) CH3COOH
(c) CH3COCH3
(d) CH3CHO
Answer : A
Question. Structural formula of ethyne is
(a) CH3−C≡C−H
(b) H−C≡C−H
(c) H2−C=C−H2
(d) H3−C−C−H3
Answer : B
Question. Solubility of alcohol in water is due to
(a) low density of alcohol
(b) volatile nature of alcohol
(c) ionisation
(d) hydrogen bonding
Answer : D
Question. C3H8 belongs to the homologous series of
(a) Alkynes
(b) Alkenes
(c) Alkanes
(d) Cyclo alkanes
Answer : C
Question. Ethanol reacts with sodium and forms two products. These are
(a) sodium ethanoate and hydrogen
(b) sodium ethanoate and oxygen
(c) sodium ethoxide and hydrogen
(d) sodium ethoxide and oxygen
Answer : C
SOURCE BASED QUESTIONS:
1. One chemical property that all alkanes have in common is that they burn very exothermically. They make good fuels. Controlling their availability and cost can have great political consequences. When they burn in a good supply of air the products are carbon dioxide and water vapour.
Methane + oxygen --------→ carbon dioxide and water
Methane forms the major part of natural gas. Propane and butane burn with very hot flames and are sold as liquefied Petroleum gas. They are kept as liquids under pressure but they vaporize easily when the pressure is released.
i) Why do alkanes make good fuels?
Answer : Alkanes react with oxygen to produce CO2 and H2O and a large amount of heat.
ii) What are the constituents of cooking gas?
Answer : Propane and butane
iii) Write the balanced equation for the combustion of ethane.
Answer : C2H4 + 3O2 -------→ 2CO2 + 2H2O
2 The addition of hydrogen across C =C is known as hydrogenation. Ethene reacts with hydrogen, if the heated gases are passed together over a catalyst nickel ethane is the product.
Hydrogenation reactions similar to the reaction with Ethene are used in the manufacture of margarine from vegetable oils. The vegetable oils of interest
include corn oil and Sunflower oil. They are edible oil and contain long chain organic acids. The hydrocarbon chain of these acids contains one or more C= C
double bonds: they are unsaturated molecules. Oil such as Sunflower oil are rich in poly and saturated molecules. This means that the melting point is relatively low and the oil remains liquid at normal temperature. By hydrogenation some but not all of the C=C double bonds, the liquid vegetable oil can be made into a solid but spreadable fat.
Animal fat tend to be more saturated than vegetable oils and fats. The animal fats in cream can be made into butter. Mini doctors now believe that unsaturated fats are more healthy then saturated fats.
i) Why are corn oil and sunflower oil called unsaturated molecules?
Answer : Corn oil and Sunflower oil contain long chain organic acids with some of the C- C double bonds.
ii) Which is better for human consumption- Animal fat or vegetable fat? Why?
Answer : Vegetable fat as they are unsaturated
iii) How is ethane produced from ethene? Give the equation.
Answer : C2H4 + H2 -nickel--heat---→ C2H6
Very Short Answers :
Question. What is Allotropy?
Answer: It is a property due to which an element can exist in more than one form which differ in physical properties but have similar chemical properties, e.g., carbon, sulphur, phosphorus, oxygen show allotropy.
Question. What are organic Compounds?
Answer: Those compounds which consist of carbon essentially and hydrogen mostly along with other elements like oxygen, sulphur, nitrogen, halogens, etc., are called organic compounds.
Question. What is Vital Force Theory?
Answer: It was proposed that ‘vital force’ is necessary for formation of these organic compounds. They can only be obtained from living organisms.
Question. Which gas is present in biogas and CNG?
Answer: Methane
Question. Name three allotropes of carbon.
Answer: Diamond, graphite and Buckminster fullerenes
Question. Which is the purest allotrope of carbon?
Answer: Buckminster fullerenes.
Question. Why is graphite soft and slippery?
Answer: Due to weak van der Waals’ forces of attraction between hexagonal layers.
Question. Write the molecular formula of first two members of homologous series with functional group —OH.
Answer: Methanol (CH3OH) and Ethanol (CH3CH2OH).
Question. Why is diamond hard?
Answer: It is due to strong covalent bonds.
Question. What will be the product formed when carbon is burnt in presence of air?
Answer: Carbon dioxide
Question. Give name of one cyclic hydrocarbon.
Answer: Cyclohexane
Question. Covalent compounds have low melting and boiling point. Why?
Answer : Covalent compounds have low melting and boiling points because they are made up of electrically neutral molecules. So, the force of attraction between the molecules of a covalent
compound is very weak.
Question. Write the molecular formula of the first two members of the homologous series having functional group —COOH.
Answer : The molecular formula of the first two members of the homologous series having functional group —COOH is HCOOH and CH3COOH
Question. What is the difference in the molecular mass of any two adjacent homologues?
Answer : Two successive homologues would differ by one carbon atom and two hydrogen atoms in terms of atoms in their molecules and thus differ by 14 amu in terms of molecular mass.
Answer : A hydrocarbon in which at least two carbon atoms are joined by a double (=) or a triple ( ≡ ) bond, is called an unsaturated compound.
Question. Write the molecular formula of (i) Methane and (ii) Ethanol.
Answer : The molecular formula of
(i) Methane: CH4
(ii) Ethanol: C2H5OH
Short Answers :
Question. Explain, giving reason, why carbon neither forms C4+ cations nor C4– anions, but forms covalent compounds which are bad conductors of electricity and have low melting point and low boiling point.
Answer : Carbon could form C4+ cation by losing four electrons, but it would require a large amount of energy to remove four electrons leaving behind a carbon cation with six protons in its nucleus holding on to just two electrons. Carbon could form C4– anion by gaining four electrons, but it would be diffcultforthenucleus with six protons to hold on to ten electrons, that is, four extra electrons. Therefore, carbon forms covalent bonds with other atoms by sharing electron pairs and in this process both atoms attain the noble gas configuration. Covalent compounds are generally poor conductors of electricity since the electrons are shared between atoms and no charged particles are formed. Covalent compounds have generally low melting and boiling points as the intermolecular forces are weak.
Question. What are the two properties of carbon which lead to the huge number of carbon compounds we see around us?
Answer : Carbon form large number of compounds due to the following properties:
(a) Catenation → Carbon shows the property of catenation that is the ability to form bonds with other carbon atoms forming long chains both branched and unbranched chains, and even rings.
(b) Tetravalency → Carbon has valency 4, it is capable of bonding with 4 other carbon atoms or atoms of other non-covalent elements, giving rise to compounds with specific properties depending on the elements present in the compound.
(c) Isomerism → Carbon compounds show the property of isomerism that is compounds having same molecular formula but different structural formula.
Question. How would you distinguish experimentally between an alcohol and a carboxylic acid?
Answer : (a) Acid test: Reaction with carbonates/hydrogen carbonates. Take samples of alcohol and carboxylic acid in 2 test tubes, and add sodium carbonate or sodium bicarbonate solution to each. The compound which will produce brisk effervescence of CO2 gas will be acid.
(b) Alcohol test: Take small amount of ethanol and ethanoic acid in test tube A and B. Add 5% solution of alkaline potassium permanganate drop by drop to this solution and warm the test tube.
The colour of potassium permanganate will disappear in test tube containing alcohol.
Question. Draw the structures for the following compounds.
(i) Ethanoic acid (ii) Bromopentane
(iii) Butanone (iv) Hexanal Are structural isomers possible for bromopentane?
Answer :
Question. What are oxidising agents?
Answer : The compounds which add oxygen to other substance are known as oxidising agent.
For example, alkaline potassium permanganate solution and acidified potassium dichromate, both can convert alcohol into carboxylic acid, i.e., ethanoic acid.
Question. How would you name the following compounds:
Answer : (i) Bromo ethane (ii) Methanal
(iii) Hex-1-yne
Question. Why is the conversion of ethanol to ethanoic acid an oxidation reaction?
Answer : Conversion of ethanol to ethanoic acid is an oxidation reaction because oxygen is added to ethanol to convert it to ethanoic acid.
In the above reaction alk. KMnO4/acidified K2Cr2O7 add oxygen to ethanol hence they are called oxidising agent.
Question. A mixture of oxygen and ethyne is burnt for welding. Can you tell why a mixture of ethyne and air is not used?
Answer : If air is used, incomplete combustion will take place giving a sooty flame and less heat is produced. When pure oxygen is used ethyne burns completely producing large amount of heat and blue flame. This heat is sufficient for a metal to melt and welding is done.
Question. How many structural isomers can you draw for pentane?
Answer : Three structural isomers can be drawn from pentane.
Pentane : C5H12
Question. What would be the formula and electron dot structure of cyclopentane?
Answer : The formula of cyclopentane is C5H10.
The electron dot structure is
Question. Would you be able to check if water is hard by using detergent?
Answer : No, because detergent forms lather in both, hard and soft water.
Question. What would be the electron dot structure of carbon dioxide which has the formula CO2?
Answer : The electron dot structure of CO2 is
Question. People use variety of methods to wash clothes. Usually after adding the soap, they ‘beat’ the clothes on a stone, or beat it with a paddle, scrub with a brush or the mixture is agitated in a washing machine. Why is agitation necessary to get clean clothes?
Answer : Soap lowers the surface tension of water. The long chain non-ionic hydrocarbon group in soap gets attached to the oil or grease droplets and loosens them from the fibres of cloth along with the dirt. However this loosening is insufficient to remove the grease with dirt completely. Hence the clothes are agitated to remove the grease droplets completely.
Question. Unsaturated hydrocarbons contain multiple bonds between the two c-atoms and show addition reaction. Give the test to distinguish ethane from ethene.
Answer : To distinguish between saturated and unsaturated hydrocarbons, a combustion test should be performed. A saturated hydrocarbon undergoes complete combustion and burns with blue flame. Also, it does not leave any residue behind after burning. On the contrary, an unsaturated hydrocarbon undergoes incomplete combustion and burns with yellow flame. Also, it leaves some residue behind after burning. Ethane is a saturated hydrocarbon. Thus, it burns with a blue flame and does not leave a residue behind. Ethene is an unsaturated hydrocarbon. Thus, it burns with a yellow flame and leaves some residue behind.
Question. Why does carbon become stable after sharing four electrons? What type of bond is formed by sharing?
Answer : The element carbon has atomic number as ' and its electronic configuration is 2,4 and it is tetravalent. Thus, carbon has 4 valence electrons. It can neither gain nor lose 4 electron to acquire the nearest noble gas configuration. Only way is to share the four valence electrons with the electrons of other atoms The type of bond formed by sharing of electrons is covalent bond.
Question. Catenation is the ability of an atom to form bonds with other atoms of the same element. It is exhibited by both carbon and silicon. Compare the ability of the catenation of the two elements. Give reasons.
Answer : Catenation is the ability of an atom to form bonds with other atoms of the same element. It is exhibited by both carbon and silicon. Carbon exhibits catenation much more than silicon in- fact no other element exhibits the property of catenation to the extent seen in carbon compounds. Silicon forms compounds with hydrogen which have chains of upto seven or eight atoms, but these compounds are very reactive. The carbon- carbon bond is very strong and hence stable. This gives us the large number of compounds with many carbon atoms linked to each other. Carbon has a valency of four and it is capable of bonding with four other atoms of carbon or atoms of some other mono-valent element. The bonds formed by carbon atoms are very strong and do not break easily so carbon compounds are stable.
Question. What are covalent compounds? How are they different from ionic compounds? List any two properties of covalent compounds.
Answer : Covalent compounds are the compounds formed by the sharing of electron pairs between two atoms. Covalent compounds have covalent bonds between atoms. Ionic compounds are formed due to strong electrostatic interactions between ions formed by the transfer of electrons. Ionic compounds have ionic or electrovalent bonds between atoms. Properties of covalent compounds: (1) These compounds have low melting and boiling points. (2) They are generally poor conductors of electricity. (3) Covalent compounds are usually insoluble in water.
Question. What is a homologous series of carbon compounds? List its any two characteristics. Write the name and formula of the next higher homologous of HCOOH.
Answer : Homologous series is a series of carbon compounds in which the hydrogen in a carbon chain is replaced by the same functional group. Characteristics of homologous series are: (1) All members of a homologous series can be represented by the same general formula. For ex, the general formula for alkanes is CnH2n+2, where n is the number of carbon atoms. (2) They have similar chemical properties. (3) Any two adμacent homologues differ by CH2 in their molecular formula. (4) The difference in the molecular masses of any two adjacent homologues is 14 u. (μ) All the compounds belonging to the same homologous series have similar chemical properties. (6) The members of a homologous series show a gradual change in their physical properties with increase in molecular mass.
Question. A student reports the police about the illegal vending of alcohol near his school. He also knew about denatured alcohol.
i. What is denatured alcohol?
ii. What would happen if somebody consumes denatured alcohol?
Answer : i. Denatured alcohol is ethanol made unfit for human consumption by adding one or more chemicals (denaturants) to it. Denaturing refers to removing a property from the alcohol (being able to drink it), not to chemically altering or decomposing it, so denatured alcohol contains ordinary ethyl alcohol.
ii. If someone consumes denatured alcohol, it results in coagulation of protoplasm causing acute nausea, blindness and even death.
Long Answers :
Question. An organic compound ‘X’ with a molecular formula C2H6O undergoes oxidation in the presence of alkaline KMnO4 and forms the compound ‘Y’.
a) Identify ‘X’ and ‘Y’.
b) Write your observation when the compound ‘X’ is made to react with compound ‘Y’ which is used as a preservative for pickles.
Answer : a) X is ethanol and Y is ethanoic acid
b) C2H5OH + CH3COOH ------Conc. H2SO4-----→ CH3COOC2H5 + H2O
Question. What is the difference between soaps and detergents? State in brief the cleansing action of soaps in removing an oily spot from a fabric. Why are soaps not effective when a fabric is washed in hard water? How can this problem be resolved?
Answer : a) Soaps are the sodium or potassium salts of higher fatty acids. Synthetic detergents are the sodium salts of a long chain alkyl benzene sulphonic acids or long chain alkyl hydrogen sulphates. soap molecule contains a polar part (COO–Na+) called polar end and a non-polar part consisting of a long chain carbon atom. This part is called hydrocarbon end.
The polar end is water soluble whereas hydrocarbon part is water-repellent and oil soluble. When an oily (dirty) piece of cloth is put into soap solution, the hydrocarbon part of the molecule attaches itself to the oily drop and the -COO– end orients itself towards water. Na+ ions in solution arrange themselves around the -COO– ions. The negatively charged micelle so formed entraps the oily dirt. The negatively charged micelle repel each other due to the electrostatic repulsion. As a result, the tiny oily dirt particles do not come together and get washed away in water during rinsing. In hard water, soap does not form lather as hard water contains Ca2+and Mg2+ ions. Soap reacts with these ions to form insoluble calcium and magnesium salts of fatty acids.
Detergents can form lather well even in hard water as they do not form insoluble calcium or magnesium salts.
Question. 6.1ml glacial acetic acid and 1ml of ethanol are mixed together in a test tube. Few drops of concentrated sulphuric acid are added in the mixture are warmed in a water bath for 5 min
a) Name the resultant compound formed.
b) Represent the above change by a chemical equation.
c) What term is given to such a reaction.
d) What are the special characteristics of the compound formed?
Answer : a) It gives an ester called ethyl ethanoate.
b) C2H5OH + CH3COOH ------Conc. H2SO4-----→ CH3COOC2H5 + H2O
c) Esterification reaction
d) It is sweet smelling. It is used in perfumes and as a flavouring agent.
Question : While cooking, if the bottom of the vessels is getting blackened on the outside, it means that:
b. Mg(HCO3)2
c. CaCl2
d. CaSO4
CASE STUDY BASED QUESTIONS:
1. Read the following and answer the questions :
The compounds which have the same molecular formula but differ from each other in physical or chemical properties are called isomers and the phenomenon is called isomerism. When the isomerism is due to difference in the arrangement of atoms within the molecule, without any reference to space, the phenomenon is called structural isomerism. In other words. structural isomers are compounds that have the same molecular formula but different structural formulas, i.e., they are different in the order in which different atoms are linked. In these compounds,carbon atoms can be linked together in the form of straight chains, branched chains or even rings.
Question : Which of the following sets of compounds have same molecular formula?
(a) Butane and iso-butane
(b) Cyclohexane and hexene
(C) Propanal and propanone
(d) All of these
Answer: D
Question : In order to form branching, an organic compound must have a minimum of carbon atoms
(a) 2
(b) 3
(c) 4
(d) 5
Answer: C
Question : Which of the following is an isomeric pair?
(a) Ethane and propane
(b) Ethane and ethene
(c) Propane and butane
(d) Butane and 2-methylpropane
Answer: A
Question : Among the following the one having longest chain is
(a) neo-pentane
(b) iso-pentane
(C) 2-methylpentane
(d) 2,2-dimethylbutane
Answer: C
Question : The number of isomers of pentane is
(a) 2
(b) 3
(c) 4
(d) 5
Answer: B
2. Read the following and answer the questions :
Food, clothes, medicines, books, or many of the things are all based on this versatile element carbon. In addition, all living structures are carbon based. The earth’s crust has only 0.02% carbon in the form of minerals. The element carbon occurs in different forms in nature with widely varying physical properties. Both diamond and graphite are formed by carbon atoms, the difference lies in the manner in which the carbon atoms are bonded to one another. Carbon has the unique ability to form bonds with other atoms of carbon, giving rise to large molecules. This property is called catenation.
Question : From the given alternatives, whose chemical and physical properties are not same?
(a) Graphite and Diamond
(b) Phosphorous and Sulphur
(c) Carbon and Hydrogen
(d) Methyl alcohol and Acetic acid
Answer: D
Question : Which of the following statements is not correct?
(a) Graphite is much less dense than diamond
(b) Graphite is black and soft
(c) Graphite has low melting point
(d) Graphite feels smooth and slippery
Answer: C
Question : Which of the following are isomers?
(a) Butane and isobutene
(b) Ethane and ethene
(c) Propane and propyne
(d) Butane and isobutane
Answer: D
Question : Which one of the following is not an allotrope of carbon?
(a) Soot
(b) Graphite
(c) Diamond
(d) Carborundum
Answer: D
Question : Pentane has the molecular formula C5H12. It has
(a) 5 covalent bonds
(b) 12 covalent bonds
(c) 16 covalent bonds
(d) 17 covalent bonds
Answer: C
Very Short Answers
Question : What will happen to the litmus solution in carboxylic acid?
Answer : Red litmus remains the same but blue litmus changes to red.
Question : What happens when ethanol burns in air?
Answer : Ethanol burns to form carbon dioxide and water.
Question : A compound has a molecular formula C2H6O. It is used as a fuel. Name the compound and name its functional group.
Answer : C2H6O is an alcohol, i.e. ethanol C2H5OH
Functional group is —OH.
Question : Draw the electron dot notation of O2 molecule.
Answer:
Question :Identify the functional group present in the following compound:
Answer:-Aldehyde.
Question : Write the name and formula of the 2nd member of homologous series having general formula CnH2n
Answer: CnH2n : Alkene , 2nd member = C3H6 (propene)
Question : Write the molecular formula of an alkyne containing 10 atoms of hydrogen.
Answer: C6H10.
Question : What is the function of conc. H2SO4 in the formation of ethene from ethanol?
Answer: Dehydrating agent
Short Answers
Question : What would be the electron dot structure of carbon dioxide which has the formula CO2?
Answer: The atomic number (Z) for carbon is six and its electronic configuration is 2, 4. Carbon has four valence electrons.
Each oxygen atom (Z = 8) has six valence electrons (2, 6). In order to complete its octet, the carbon atom shares its four valence electrons with the four electrons of the two
oxygen atoms as follows :
Thus, in carbon dioxide molecule, the carbon atom is linked to two oxygen atoms by two shared pairs of electrons resulting in double bonds on either sides. Both carbon and oxygen
atoms complete their octet as a result of electron sharing.
Question : Why is homologous series of carbon compounds so called? Write the chemical formula of two consecutive members of any homologous series and state the part of these compounds that determines their (i) physical and (ii) chemical properties.
Answer: A homologous series is the family of organic compounds having the same functional group, similar chemical properties but the successive (adjacent) members of the series are differ by a CH2 unit or 14 mass units.
Consecutive members of the homologous series of alcohols are :
CH3 OH ] They differ by CH unit.
CH3 OH
The physical properties are determined by alkyl group/ hydrocarbon part/part other than the functional group.
The chemical properties are determined by functional group such as —OH group.
Question : Define isomerism. Write down the structures and names of isomers of butane.
Answer: Two or more compounds having same molecular formula but different structural arrangements of atoms in their molecules are called isomers. This phenomenon is called
isomerism.
Question : An element X has a proton number of 15, while element Y has a proton number of 17. Draw a ‘dot-and-cross’ diagram to show all electrons in a molecule formed from elements X and Y.
Answer: Electronic configuration of X : 2, 8, 5 Atom X contributes three electrons for sharing.
Electronic configuration of Y : 2, 8, 7 Each atom of Y contributes one electron for sharing.
Therefore, three atoms of Y contribute three electrons for sharing.
One atom of X will share three pairs of electrons with three atoms of Y to achieve the noble gas configuration.
Both atoms X and Y achieve the electronic configuration of argon (2, 8, 8).
Question : (a) What type of bond holds the two chlorine atoms together in a chlorine molecule?
(b) Briefly describe how this bond is formed.
(c) Draw a ‘dot-and-cross‘ diagram to show the bonding in a chlorine molecule.
Answer: (a) Covalent bond
(b) The two chlorine atoms share one pair of electrons, so that both atoms achieve a noble gas configuration.
Question : The diagram shows one layer of carbon atoms in the structure of graphite:
(a) Identify the types of bonding in graphite.
(b) Which property of graphite makes it suitable for use as a dry lubricant? Explain your answer.
Answer: (a) Covalent bonds between carbon atoms in each layer and van der Waals’ forces between the layers of carbon atoms.
(b) Graphite is soft. The layers of carbon atoms can slide and glide over each other because the weak van der Waals’ forces between the layers are easy to overcome.
Question : Explain the nature of the covalent bond using the bond formation in CH3Cl.
Answer: The molecule of chloromethane (CH3Cl) consists of three elements i.e., carbon (Z = 6), hydrogen (Z = 1) and chlorine (Z = 17). Carbon atom has four valence electrons (2, 4) ; hydrogen has one (1) while chlorine has seven electrons in the valence shell (2, 8, 7). In order to complete its octet, carbon shares three valence electrons with three hydrogen atoms while one is shared with the electron of chlorine atom. The structure of covalent molecule may be written as follows :
Question : What is homologous series of compounds?
List any two characteristics of homologous series.
Answer: A series of compounds having similar structures and similar chemical properties in which the successive member differs in their molecular formula by –CH2 group is called homologous series.
Characteristics :
(a) All the members of homologous series have similar chemical properties.
(b) Any two consecutive members differ in their molecular formula by a –CH2 group.
Question : Two non-metals A and B combine with each other by sharing of electrons to form compound C.
(a) What is the naturstronge of compound C ?
(b) Will it dissolve in water or organic solvents?
(c) Will it be a good or bad conductor of electricity?
(d) Will it have high or low melting/boiling point ?
Answer: (a) Covalent
(b) Usually soluble in organic solvents
(c) Bad conductor
(d) Usually low melting / boiling point.
Question : What is the difference in the number of carbon and hydrogen atoms between two successive members of a homologous series? Also give the difference in their atomic masses.
Answer: The difference is of 1 carbon and two hydrogen atoms i.e., —CH2 and mass difference is 14 a.m.u.
Question : Why acetic acid is called glacial acetic acid?
Answer: Acetic acid has very low melting point i.e. 290 K, hence it freezes during winters in cold countries. So it is called glacial acetic acid.
Question : Diamond and graphite show different physical properties although they are made up of carbon and shows same chemical properties. What is this property called?
Answer: This property is allotropy.
The physical properties are different because the carbon-carbon bonding in both the cases varies. In diamond one carbon atom is bonded with four other carbon atoms with strong covalent bond so it is hard, while in case of graphite each carbon forms two strong bonds with other two carbon atoms and one weak bond is formed with third carbon atom and forms hexagonal rings which slide over each other, so it is soft.
Question : What is esterification and give its uses?
Answer: It is the reaction in which esters are formed by reacting carboxylic acid with alcohol in the presence of concentrated sulphuric acid.
Carboxylic acid + alcohol ⎯⎯→ Ester + water
C2H5OH + CH3COOH ⎯⎯→ CH3COOC2H5 + H2O
Ethanol Ethanoic acid Ester
Uses:(i) It is used as flavour in ice-cream and sweets.
(ii) It is a sweet smelling substance.
Question : (a) Give a chemical test to distinguish between saturated and unsaturated hydrocarbons.
(b) (i) Name the products formed when ethanol burns in air.
(ii) What two forms of energy are liberated on burning alcohol?
(c) Why is the reaction between methane and chlorine considered a substitution reaction?
Answer: (a) On adding bromine water, the unsaturated hydrocarbon decolourises the bromine water but the saturated hydrocarbon will not decolourise bromine water.
(b) (i) Ethanol burns in air to produce carbon dioxide and water.
C2H5OH + 3O2 ⎯⎯→ 3CO2 + 3H2O + heat
(ii) Two forms of energy obtained are heat energy and light energy.
(c) When methane reacts with chlorine, the hydrogen atom of methane is replaced by chlorine atom step by step and hence it is termed as substitution reaction.
CH4 + Cl2 ⎯⎯→ CH3Cl + HCl
Question : Covalent compounds have low melting and boiling point. Why?
Answer: Covalent compounds have low melting and boiling points because the forces of attraction between molecules of covalent compounds are very weak. On applying a small amount of heat these molecular forces break.
Question : What are covalent compounds? Why are they different from ionic compounds? List their three characteristic properties.
Answer: Covalent compounds are those compounds which are formed by sharing of valence electrons between the atoms e.g., hydrogen molecule is formed by mutual sharing of electrons between two hydrogen atoms.
They are different from ionic compounds as ionic compounds are formed by the complete transfer of electrons from one atom to another e.g., NaCl is formed when one valence electron
of sodium gets completely transferred to outer shell of chlorine atom. The characteristic properties of covalent compounds are:
(i) They are generally insoluble or less soluble in water but soluble in organic solvents.
(ii) They have low melting and boiling points.
(iii) They do not conduct electricity as they do not contain ions.
Question : What are covalent bonds? Show their formation with the help of electron dot structure of . Why are covalent compounds generally poor conductors of electricity?
Answer: Covalent bonds are those bonds which are formed by sharing of the valence electrons between two atoms. Electron dot structure of methane is shown in the figure.
Covalent compounds are generally poor conductors of electricity because they do not have tree electrons or ions.
Question : Give reasons for the following:
(i) Element carbon forms compounds mainly by covalent bonding.
(ii) Diamond has high melting point.
(iii) Graphite is a good conductor of electricity.
Answer: (i) As carbon has four valence electrons and it can neither lose nor gain four electrons thus, it attains noble gas configuration only by sharing of electrons. Thus, it forms covalent compounds.
(ii) In diamond, each carbon atom is bonded to four other carbon atoms forming a rigid threedimensional structure. This makes diamond the hardest known substance. Thus, it has high melting point.
(iii) In graphite, each carbon atom is bonded to three other carbon atoms by covalent bonds in the same plane giving a hexagonal array. Thus, only three valence electrons are used for bond formation and hence, the fourth valence electron is free to move. As a result, graphite is a good conductor of electricity.
Question : Write the next homologue of each of the following:
(i) C2H4
(ii) C4H6
Answer: (i) C2H4 belongs to alkene series having general formula, CnH2n.
Thus, next homologue will be C3H2×3 = C3H6
(ii) C4H6 belongs to alkyne series having general formula, CnH2n-2.
Thus, next homologue will be C5H2×5-2 = C5H8
Question : Name the following compounds:
Answer:
Question : Write the name and structure of an alcohol with three carbon atoms in its molecule.
Answer: An alcohol with three carbon atoms in its molecule is propanol. The structure of propanol is
Long Answers
Question : Why carbon and its compounds are used as fuels for most applications?
Answer: Carbon and its compounds give large amount of heat on combustion due to high percentage of carbon and hydrogen. They have high optimum ignition temperature with high calorific values and are easy to handle and their combustion can be controlled. Therefore, carbon and its compounds are used as fuels.
Question : What is meant by isomers? Draw the structures of two isomers of butane. Explain why we cannot have isomers of first three members of alkane series?
Answer: Isomers are compounds having the same molecular formula but different structures. Since branching is not possible, isomers are not possible for the first three members of alkanes series.The two isomers of butane, C4H10 are:
Question : State the reason why carbon can neither form C+4 cation nor C-4 anions but forms covalent compound.
Answer: Carbon has atomic number 6. This means that it has 4 electrons in its outermost shell. It needs to gain or lose 4 electrons to achieve noble gas configuration. But it cannot form C+4 cation because the removal of 4 electrons requires a large amount of energy. And also, cannot form C-4 anion as it would be difficult for its nucleus with 6 protons to hold on to 10 electrons. Therefore, Carbon atoms share electrons and form covalent compounds
Question : What is a homologous series? List any of its two features.
Answer: A homologous series is a series of carbon compounds that have different numbers of carbon atoms but contain the same functional group.
Characteristics of homologous series:
1. The members of the homologous series can be represented by a general formula.
2. The successive members differ from each other in the molecular formula by a CH₂ unit.
Question : The element carbon forms a very large number of compounds. Give reason for this fact.
Answer: Carbon forms large number of compounds because of tetravalency and catenation property.
Tetravalency- Carbon has valency 4 to attain noble gas configuration carbon shares its valence electrons with other elements like hydrogen chlorine etc.Catenation-Carbon also shows the property of self-linking in which it forms long branched or cyclic chains to form large number of compounds.
Question : List Any three difference between soap and detergent.
Answer:
soap detergent
i) Soaps are sodium salts of fatty acids. Detergents are sodium salt of sulphonic acids.
ii) Soaps clean well in soft water but detergents clean well with both with
do not clean well in hard water hard and soft water
Soaps are biodegradable and do not Some detergents are nonbiodegradable
cause pollution. and cause of pollution
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Worksheet for CBSE Science Class 10 Chapter 4 Carbon and Its Compound
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